The cigarette smoke which emanates from the cigarette tip is actually Blue in color. The smoke which is puffed out, on the other hand, is White! Why? This has everything to do with particle size! The smoke from cigarette is blue for the same reason the sky is blue. The smoke particles are small and as a consequence of which blue light out of all the other wavelengths of light get scattered the most. Hence, you see the smoke to be Blue! ( known as Rayleigh Scattering ) The smoke which is puffed out from the lungs has moisture in it. And the presence of water molecules in smoke increases particle size. With an increased particle size, all wavelengths of light get scattered to the same proportions. Hence, you see the smoke as White! There is physics which lurks even in the smoking zone! PC: Univeristy of Hartford, isciencetimes.